Por favor, use este identificador para citar o enlazar este ítem:
http://ciatec.repositorioinstitucional.mx/jspui/handle/1019/160| Nucleating Effect of Carbon Nanoparticles and Their Influence on the Thermal and Chemical Stability of Polypropylene | |
| ROBERTO ZITZUMBO GUZMAN | |
| Acceso Abierto | |
| Atribución-NoComercial | |
| Polímeros Polipropileno | |
| The effect of carbon nanofibers (CNFs) and carbon nanotubes (CNTs) on the thermal and chemical stability of polypropylene (PP) when subjected to oxidation in a strong acid medium was studied. The effect of CNFs and CNTs on the crystalline morphology and the melting and crystallization temperatures was also studied. The thermal stability increased markedly; the decomposition temperature, for example, increased from 293◦C for pure PP to 312 and 320◦C for PP with CNFs and CNTs, respectively. The crystallization temperature increased perceptibly with the addition of CNTs or CNFs, from 107◦C for pure PP to 112 and 114◦C for PP with CNFs and CNTs, respectively. The oxidative degradation with nitric acid produced a reduction in molecular weight; however, this negative effect was less pronounced in the PP compositions with carbon nanoparticles. After 8 hours in nitric acid, this reduction was from 141,000 to 68,000 (for pure PP), to 75,000 (for PP-CNFs), and 79,500 (for PP-CNTs). X-ray diffraction showed that the alpha type crystallinity remains, irrespective of the nucleating agent. Finally, the intensity ratio between the (040) (at 16.7◦) and the (110) (at 13.9◦) reflections increased, which was taken as an indication of an increasing nucleating efficiency. | |
| 2012 | |
| Artículo | |
| Inglés | |
| Empresas Estudiantes Investigadores Maestros | |
| PROCESOS INDUSTRIALES | |
| Versión publicada | |
| publishedVersion - Versión publicada | |
| Aparece en las colecciones: | Artículos de investigación |
Cargar archivos:
| Fichero | Tamaño | Formato | |
|---|---|---|---|
| Nucleating.pdf | 1.94 MB | Adobe PDF | Visualizar/Abrir |